A new palladium complex with N-heterocyclic carbene (NHC) and phosphine ligands was prepared and fully characterized by 1 H NMR, 13C NMR and 31P NMR spectroscopies, IR spectroscopy, and X-ray crystallography. The solid-state structure of the complex shows that the metal centre was surrounded by an N-heterocyclic carbene ligand, a phosphorus atom and two bromide ions in a cis-arrangement. Density functional theory (DFT) calculations at the B3LYP/SDD level were also executed for the further explorations of the spectroscopic and structural properties. The obtained theoretical parameters adequately support the experimental findings in general.
Synthesis, structural, spectroscopic and DFT study on a palladium(II)- N-heterocyclic carbene complex
Posted by
Rukiye Firinci
on 12 09 2020
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